* 25L refers to volume, meaning the amount of space the cat litter occupies.
* 25KG refers to weight, meaning how heavy the cat litter is.
To know which is "most" you need to consider what you're looking for:
* If you need more litter by volume, then a 25L bag would be more than a 25KG bag (assuming the density of the litter is the same).
* If you need more litter by weight, then a 25KG bag would be more than a 25L bag.
You need to check the specific product packaging to see how much volume a 25KG bag of cat litter occupies, or how much weight a 25L bag of cat litter has.