Is there a crayon called purple people eater?

There is no crayon called "Purple People Eater".

That phrase is actually the name of a popular 1958 novelty song by Sheb Wooley. The song itself is about a fictional creature that eats people. It's unlikely a crayon would be named after such a song, especially considering its humorous and slightly spooky nature.

Crayon manufacturers usually name their crayons after colors or objects, like "Blue" or "Apple".